Flat Rare Earth Element Patterns Research Articles

A hydrous sub-arc mantle domain within the northeastern Neo-Tethyan ophiolites: Insights from cumulate hornblendites

Being a part of the large-scale Indus-Tsangpo suture zone ophiolites of the Alpine-Himalayan orogenic system, the Neo-Tethyan ophiolites of eastern Arunachal Himalaya, northeast India, are important in understanding the formation and evolution of the Neo-Tethyan lithosphere. This study focuses on the hornblendite dykes occurring within serpentinized peridotites of the Mayodia ophiolites in eastern Arunachal Himalaya, to ascertain the origin and evolution of such hydrous mineral cumulates within the ophiolite complex. Texturally and chemically, the hornblendites contain three types of amphiboles, Amp1 (pargasite), Amp2 (Mg-hornblende), and Amp3 (actinolite). The pargasites occur as large cm-sized phenocrysts and show cumulate textures while Mg-hornblende appears as both intercumulus grains between cumulus pargasites and surrounding partially resorbed clinopyroxene grains. Actinolite occurs along the breakdown zone of pargasite and is associated with other secondary minerals. The hornblendites are characterized by high MgO (~12–20 wt%) and low SiO2 (~42–44 wt%) with depleted light rare earth elements (REE) [(La/Sm)N = 0.29–0.52] and almost flat heavy REE [(Gd/Yb)N) = 0.89–1.11]. Moreover, the samples are characteristically depleted in high field strength elements (Nb, Ta, Ti, Hf) while being enriched in Pb. Geothermobarometric calculations yield high magmatic temperatures of ~950 and ~ 840 °C for pargasite and Mg-hornblende, respectively, and variable pressures with pargasite having the highest pressures (1.6–1.7 GPa) followed by Mg-hornblende (1.1–1.2 GPa) and finally actinolite (~0.55 GPa). Furthermore, fO2 calculations for the cumulus pargasites revealed highly oxidizing conditions (ΔNNO+2) and water content of parental melts (H2Omelt% = ~14.25 %). Parental melt calculations using whole-rock REE concentrations suggest formation from a hydrous sub-alkaline basaltic melt. Whole-rock initial SrNd isotopic ratios of the hornblendites reveal a primary signature for them, falling in the mantle array in proximity to the high-μ (HIMU) mantle reservoir. All these signatures point towards a magmatic arc affinity for these hornblendites. The host peridotite unit shows highly enriched REE concentrations (ƩREE = 18.13 ppm) with flat REE patterns compared to the other peridotites of the locality, which show depleted signatures. Olivine chemistry of the host peridotite unit depicts primary compositions falling in the mantle array. The olivine-liquid thermometer yields temperatures ~1000 °C, which are much lower than those of peridotites occurring in spreading centers (MOR or back-arc). These evidence suggest that the hornblendites and their host peridotite unit represent an island arc root complex, which further imply the hydrous nature of the Neo-Tethyan sub-arc mantle.

Mineralogy and element geochemistry of the Bayan Obo (China) carbonatite dykes: Implications for REE mineralization

The Bayan Obo deposit in China is the world's largest rare earth element (REE) deposit. However, its genesis remains highly debated. It is considered to have a close genetic association with carbonatites because of the presence of nearby carbonatite dykes and the geochemical similarities between these dykes and the orebody. However, the evolution of these dykes and associated REE mineralization remain poorly understood, hindering the origin interpretation of the deposit. This study provides new insights into the petrography, mineralogy, and major- and trace-element geochemistry of these carbonatite dykes and rock-forming minerals to reconstruct the magmatic evolution and REE enrichment of the deposit. The dykes evolved from dolomite- to calcite-dominated (i.e., calcite and fenitized calcite) carbonatites, and their REE content remarkably increased, with the latter developing strong REE mineralization. The dolomites and minor calcites within the dolomite carbonatites exhibit a steep negative slope with high light REE (LREE) enrichment and heavy REE (HREE) depletion, similar to the whole rock. In contrast, the calcites from the calcite-dominated carbonatites exhibit flat REE patterns with HREE enrichment. Combined with previous isotopic data and our petrology, mineralogy, and geochemistry study, we propose that these rocks are derived directly from the low-degree melting of the underlying mantle source. REE mineralization may be related to the progressive crystallization of rock-forming calcites of calcite-dominated carbonatites. Monazite, bastnäsite, parisite, and huanghoite are the dominant REE minerals and exhibit intimate associations with barite and alkaline silicate minerals such as aegirine, biotite, K-feldspar, and albite. This assemblage indicates that the REE were primarily transported via REE–sulfate and REE–alkali complexes, with the latter favoring HREE, and the precipitation of alkaline silicate minerals destabilized these REE complexes, facilitating REE mineralization.

Processes controlling rare earth element distribution in sedimentary apatite: Insights from spectroscopy, in situ geochemistry and O and Sr isotope composition

ABSTRACTIn phosphorites, the content and distribution of rare earth elements are linked to the environment of phosphogenesis. This paper focuses on the question of sources and processes controlling the rare earth element content of apatite from Belgian phosphorites formed during three major phosphogenic events in the Lower Palaeozoic, Late Cretaceous and Cenozoic. To constrain sources and processes, new data include petrological, mineralogical (including cathodoluminescence and Raman spectroscopy) and in situ trace element and Sr and O isotope analyses of apatite. Fluorapatite from Lower Palaeozoic P‐rich conglomerates has the greatest rare earth element enrichment. It is affected by metamorphism that led to deformation of apatite nodules and formation of garnet porphyroblast inclusions. The role of Fe‐oxyhydroxides in element scavenging is highlighted by some apatite nodules that maintain their primary middle rare earth element enrichment, while others are characterized by altered rare earth element patterns resulting from competition for these elements between co‐crystallizing minerals during deformation. A systematic shift towards lower δ18O and radiogenic Sr isotopic composition compared to contemporaneous seawater indicate interaction with 18O‐depleted meteoric fluids and a crustal component. By contrast, carbonate‐rich fluorapatite from the Late Cretaceous phosphatic chalk mostly keeps its primary trace element and isotopic signatures (close to seawater), although an external rare earth element addition is noted, as well as rare earth element redistribution induced by diagenetic alteration. Cenozoic carbonate fluorapatite nodules mostly present flat rare earth element patterns that are indicative of a detrital influence. Slight changes in rare earth element distribution are assigned to post‐depositional alteration, which also led to an increase in radiogenic Sr, with unchanged δ18O compared to seawater. The methodology followed here efficiently helps in deciphering the processes that modified the chemistry of apatite in the frame of major phosphogenic events.

Neoarchaean DTTGs from the Dunhuang Block, Tarim Craton: insights into petrogenesis and crust–mantle interactions

ABSTRACT Earth’s first continental crust is formed by Archaean and mainly consisted of tonalite–trondhjemite–granodiorite with a small amount of diorites (DTTGs), which has an essential role in probing early crust–mantle dynamic regime and in understanding the formation mechanism of continental crust. Here, we present zircon U‒Pb dating and Lu‒Hf isotopes, whole-rock geochemistry, and petrography on DTTGs rocks in the Dunhuang Block. Three episodes of DTTGs were emplaced circa 2.67 Ga, 2.60 Ga, and 2.50 Ga. The circa 2.67 Ga TTGs exhibit high SiO2 contents (68.14–71.70 wt%), low MgO contents (0.65–1.31 wt%), and high ratios of (La/Yb)N (146 on average), with their enriched Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t) = -5.77–0.53], indicating origination from partial melting of amphibolites at thickened lower crust. In contrast, the circa 2.60 Ga transitional TTGs exhibit relatively high MgO contents (2.80–3.39 wt%), flat REE (Rare earth element) patterns with moderate ratios of (La/Yb)N (20.49 on average), and dispersed Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t)= −3.99–3.08]. Accordingly, circa 2.60 Ga transitional TTGs melts were produced by partial melting of the shallower crust induced by mantle-derived magma upwelling. The circa 2.50 Ga diorites exhibit low SiO2 (55.72–59.11 wt%) but high MgO (3.51–4.52 wt%) contents with positive Nd-Hf isotopes [ƐHf (t) = -0.16–4.17 and ƐNd (t) = 2.00–4.45], suggesting that they originated from partial melting of mantle wedges metasomatized by fluid from subduction slabs. Combined with the detailed petrogenetic studies and crustal thickness variation, we conclude that the complex crust–mantle interaction may be an essential reason for the Neoarchaean diversity of DTTGs from the Dunhuang Block, which experienced prolonged arc accretion before Neoarchaean, followed by delamination between 2.67 and 2.60 Ga and subsequently transitioned to subduction.

Development of a back-arc basin from initial rifting to seafloor spreading: Constraints from Paleozoic basic rocks in the North Qinling accretionary orogen, central China

The progression from initial back-arc rifting to back-arc opening in ancient orogenic collages is important for reconstructing subduction histories, constraining tectonic switching, and understanding crustal growth and evolution. However, it is difficult to constrain this transition in ancient arcs. The Qinling-Dabie orogenic belt is one of the most important orogenic belts in eastern Asia, yet the history of Paleozoic accretionary processes in this belt remains equivocal, owing to a poor understanding of back-arc opening processes in the Erlangping unit. In this study, we present whole-rock geochemical analyses of mafic dikes in the Erlangping unit, along with U-Pb ages and Hf-O isotope compositions of zircon from these dikes. Zircon secondary ion mass spectrometry (SIMS) dating of these mafic dikes yielded U-Pb ages of 453 ± 3 Ma. The mafic dikes are calc-alkaline and are characterized by high K2O contents (1.16−3.16 wt%). They have enriched ([La/Yb]N = 4.3−14.9) light rare earth elements (REEs) and relatively flat heavy REE ([Dy/Yb]N = 0.9−1.5) patterns, and they exhibit enrichment in large ion lithophile elements (LILEs) but depletion in high field strength elements (HFSEs), resembling arc-like magmatism. These mafic dikes are characterized by relatively enriched initial 87Sr/86Sr (0.7049−0.7059), chondritic to slightly radiogenic εNd(t) (−0.36 to 1.33), and radiogenic whole-rock and zircon εHf(t) (+7.2−7.6 and +7.5−7.8, respectively). The zircons have δ18O values (5.0‰ ± 0.1‰) similar to those of normal mantle zircon. Accordingly, we interpret that the mafic dikes were derived from an enriched lithospheric mantle source metasomatized by subducted Proto-Tethys (Shangdan) ocean material. In contrast, previously reported ca. 440 Ma gabbros from the Erlangping unit are tholeiitic and have lower incompatible trace-element concentrations with less enrichment in LILEs and less depletion in HFSEs than the mafic dikes presented here. Whole-rock Nd and zircon Hf isotopic compositions suggest that these Silurian gabbros were derived from partial melting of a more depleted mantle with the involvement of asthenosphere, and they have a close geochemical affinity with back-arc basin basalts. In addition, trace-element ratios and geochemical modeling suggest higher melting pressures for the mafic dikes than the gabbros. The geochemical differences show systematic variations from island-arc basalt into back-arc basin basalt types, which is consistent with the magma source evolution of the Mariana Trough. Thus, we interpret that the ca. 454 Ma mafic dikes were emplaced when the infant arc split, and they record initial back-arc rifting in the Erlangping unit, whereas the Silurian gabbros subsequently formed during the opening of the back-arc basin. Our study provides a paradigm for deciphering the evolution of back-arc basins through the study of spatiotemporal geological and geochemical variations of mafic intrusions in ancient accretionary orogens.

Origin of the Paleoproterozoic basaltic dikes from the central and eastern Dharwar Craton and sills and volcanics from the adjoining Cuddapah Basin, southern India

Reverse fractionation modeling considering energy-constrained assimilation-fractional crystallization is performed to estimate primary magma compositions, degree of crustal contamination, pressure–temperature of equilibrium with mantle, and potential temperatures for the origin of the Paleoproterozoic (~ 2.37–1.88 Ga) basaltic dikes in central and eastern Dharwar Craton and sills and volcanics in the adjoining Cuddapah Basin, southern India. Mineral thermobarometry indicates that the dikes crystallized at upper crustal conditions (~ 1–6 kbar/ ~ 1120–1210 °C). Hence, the reverse fractionation calculations are performed at low pressures by adding olivine + plagioclase + clinopyroxene, olivine + plagioclase and only olivine in equilibrium with melt, and simultaneously subtracting an upper crustal partial melt in small steps until the melt is multiply saturated with lherzolite at a high pressure. The results indicate that the basalts are 5–30% contaminated, and their enriched light rare earth element (REE) patterns can be attributed to upper crustal assimilation. The upper crust was pre-heated to 665–808 °C during dike emplacement. The primary magmas of all basalts were last equilibrated with spinel lherzolite at 10–16.5 kbar/1291–1366 °C, and they resemble pooled polybaric incremental melts generated along a ~ 1450 °C adiabat. The estimated mantle potential temperatures (1293–1515 °C) are similar to Paleoproterozoic ambient mantle temperatures. All basalts and their primary magmas show lower chondrite-normalized DyN/YbN ratios than the plume-derived mid-Proterozoic Mackenzie dikes of Canadian Shield, and the primary magmas show flat REE patterns indicating spinel lherzolite melting. The low estimated potential temperatures, low DyN/YbN ratios, and a spinel-bearing mantle source are at odds with an origin of the basalts from mantle plumes.

Diachronous subduction, closure of the Proto-Tethys Ocean, and collisional accretion of microcontinents: Insights from the early Paleozoic intermediate-mafic rocks in the Amdo microcontinent of the Tibetan Plateau

The Proto-Tethys Ocean played an important role in the formation and evolution of the East Asian continental blocks, and the final closure of the Proto-Tethys Ocean may have led to the first assembly of nearly all East Asian blocks at the northern margin of Gondwana. However, controversy remains about the reconstruction of East Asian blocks at the northern margin of Gondwana. The Tibetan Plateau is located in the northern margin of Gondwana and recorded the entire tectonic evolution from continental rift and drift to subduction and collision during the early Paleozoic. Therefore, it is an important region in which to address tectonic evolution processes of the Proto-Tethys Ocean and Gondwana. Here, we present petrology, zircon U-Pb, Sr-Nd-Hf isotope, and whole-rock geochemical data from newly recognized intermediate-mafic magmatic rocks from the Amdo microcontinent of central Tibet, with a view to gain insights into the nature and geotectonic evolution of the northern margin of Gondwana. Zircon grains from meta-andesites and meta-basites in Amdo yielded magmatic crystallization ages of 490 Ma and 455−450 Ma, respectively. The meta-andesites are characterized by enrichment in large ion lithophile elements (e.g., Rb, Th, U, and K) and depletion in high field strength elements (e.g., Nb, Ta, and Ti) with positive zircon εHf(t) values (+3.4 to +6.4), which were probably derived from partial melting of a depleted mantle source enriched by minor fluids from subducted sediments in a continental arc setting. The meta-basites are tholeiitic and exhibit both mid-ocean-ridge basalt (e.g., flat rare earth element patterns) and arc-like (e.g., elevated Th/Yb ratios) geochemical affinities, in combination with negative zircon εHf(t) (−4.6 to −0.3) and whole-rock εNd(t) (−0.21 to −0.45) values, suggesting that they were probably generated by varying degrees of partial melting of a spinel peridotite source with ∼5%−10% crustal assimilation in a back-arc setting. In this regard, we favor the interpretation that the Amdo microcontinent experienced long-lasting (ca. 530−450 Ma) subduction of the Proto-Tethys Ocean slab before the subsequent collisional accretion of microcontinents. Integrating results from previous studies, we propose that the Amdo microcontinent, South Qiangtang terrane, Qilian-Qaidam terrane, and other East Asian blocks were all located at the northern margin of East Gondwana, which recorded the arc-related magmatism along the proto-Tethyan margin in the early Paleozoic. The closure of the Proto-Tethys Ocean and initial collision along the East Gondwana Proto-Tethyan margin may have been diachronous between ca. 455 and 430 Ma.

Identification of Baihesi aluminous A-type granite: Magmatic response to the onset of Cretaceous extension in eastern Jiangnan Massif, South China

The Cretaceous lithospheric extension in South China is very distinct and expressed by systematic extension-related geological records which are concentrated in the coastal terrane, Shi-Hang Rift, and Jiangnan Massif. The Cretaceous extension in the coastal terrane and Shi-Hang Rift began almost simultaneously during 145–140 Ma, while there is a lack of reliable magmatic indication for tectonic extension in the Jiangnan Massif during 145–140 Ma. This paper reports a newly discovered Baihesi granite with a concordant age of 142.52 ± 0.57 Ma (MSWD = 1.2) on the southeast margin of the eastern Jiangnan Massif with evidence from petrology, geochronology, petrochemistry and Hf isotopes. The Baihesi granite is a monzogranite and classified as a peraluminous, high-K calc-alkaline series. The trace element compositions are characterized by relatively flat rare earth element patterns; strong depletion of Eu; slightly enriched light rare earth elements; enrichment of Cs, Rb, Th, U, and Pb; and depletion of Ba, Sr, P, and Ti. Combined with other petrochemistry characteristics, such as high SiO2 content, high differentiation index, low Zr/Hf and Nb/Ta ratios, low ratio between light and heavy REEs, low P2O5 content, and high zirconium saturation temperature, Baihesi granite is proven to be highly evolved aluminous A-type granite. The εHf(t) values of Baihesi granite range from −5.57 to −2.37, with two-stage model ages (TDM2) ranging from 1,551 to 1,345 Ma, suggesting a similar source to Neoproterozoic arc-related magmatic rocks in the Shuangqiaoshan Group. We argue that Baihesi granite has originated mainly from partial melting of a reworked juvenile crust related to Neoproterozoic arc-related magmatism in the Jiangnan Massif, which was controlled by subduction along the South China active continental margin. Furthermore, we constrain the onset of Cretaceous extension in the eastern Jiangnan Massif to be 145–140 Ma and highlight the Early Cretaceous reactivation of the northeastern Jiangxi Province fault zone and the structural inheritance in intraplate tectonics.

Exotic REE behaviors of zircon in the Koktokay No. 3 granitic pegmatite, Xinjiang, northwest China

Rare earth elements (REEs) can be incorporated into zircon at significant concentrations that are controlled by the temperature, pressure, and composition of their growth environment. However, the distribution of REEs between zircon and melt does not always conform to the currently available partitioning data. This study presents evidence of exotic REE behaviors in zircon from the marginal zone of the Koktokay No. 3 granitic pegmatite in Xinjiang, northwest China. The behavior of the Koktokay REEs represents by large negative Ce anomalies, flat heavy REE patterns, and lanthanide tetrad effects. Two generations of zircon (Zrn-I and Zrn-II) are identified, which were formed by dissolution and re-precipitation processes. Zrn-I represents relic zircon domains with dissolution textures that formed from pegmatite melt during the late stage of the magmatic–hydrothermal transition. Zrn-II occurs as overgrowths and infilling fractures around or within Zrn-I, which formed by hydrothermal re-precipitation. From Zrn-I to Zrn-II, the zircon exhibits increasingly negative Ce anomalies and greater enrichment in light REEs and other non-stochiometric elements (e.g., Ca, Al, Fe, and Mg). Given the lack of Ce depletion in the host granite, the negative Ce anomalies in zircon can be attributed to Ce being sequestered into hydrothermal minerals (i.e., cerianite and/or Fe–Mn oxyhydroxides) as tetravalent Ce. In addition, the flat heavy REE patterns of both Zrn-I and Zrn-II likely resulted from the crystallization of heavy REE-enriched minerals, such as zircon and garnet, and were further enhanced by hydrothermal alteration. The two generations of zircon display identical M-type lanthanide tetrad effects in REE patterns, with similar TE3 values. This ubiquitous M-type tetrad effect of the REEs in garnet, zircon, and the host granite can be attributed to the exsolution and subsequent interaction with magmatically derived fluids containing F–aquo-complexes. Therefore, we conclude that such anomalous REE incorporation into zircon from a hydrous pegmatitic melt is controlled by the evolution of the hydrous melt and dissolution–re-precipitation processes. Our results suggest that the reliability of zircon REE partitioning data should be revaluated, and that further experimental studies are needed to fully understand the behavior of REEs in hydrothermal systems.

Growth of the continental crust induced by slab rollback in subduction zones: Evidence from Middle Jurassic arc andesites in central Tibet

Andesitic rocks have similar compositions to average continental crust and have played a central role in improving our understanding of the formation and evolution of the continental crust. Here we present data for andesites from the Jiaqiong area of the Bangong–Nujiang suture zone (BNSZ), Central Tibet. LA–ICP–MS zircon U–Pb ages demonstrate that these andesites were generated during the Middle Jurassic (169–164 Ma). The Jiaqiong andesites have variable Mg# (molar 100 × Mg/[Mg + Fe] = 35–63) values, and Cr (3.02–175 ppm) and Ni (5.70–47.7 ppm) contents. These andesitic rocks are enriched in light rare earth elements (REEs) ([La/Yb]N = 5.2–14.6) and yield relatively flat heavy REE patterns ([Gd/Yb]N = 1.4–2.1) with negative Ta, Nb, and Ti anomalies. They also have moderately high initial 87Sr/86Sr (0.7077–0.7092) ratios and variable negative εNd(t) (−11.0 to − 3.3) and zircon εHf(t) (−13.7 to + 2.1) values. These geochemical characteristics suggest that the Jiaqiong andesites were most probably produced by partial melting of mélange rocks. Combining our data with the regional geology, particularly that of nearby ophiolites and Jurassic andesitic rocks, we conclude that the formation of these andesites was triggered by asthenospheric upwelling and hot corner flow caused by the rollback of the northward-subducting Bangong–Nujiang Tethyan oceanic lithospheric slab during the Middle Jurassic. The mélanges provided the material for the formation of andesites, and probably make a substantial contribution to the vertical growth of the continental crust in subduction zones.

Geochemical Features of Volcanic Rocks from the Shaerbuti Mountain Complex, West Junggar, Xinjiang, China: Implications for Recycling of Materials

In this paper, we focus on the geological features of volcanic edifices and the geochemistry of intermediate–basic volcanic rocks of Shaerbuti Mountain, which offer a new perspective on recycled materials in the study area. The Shaerbuti volcanic rocks consist of calc-alkali basalt and andesite formed in an arc setting. The porphyroclastic texture of basalt, explosive breccia rock, and the distribution of both breccia and agglomerate provide robust evidence that a volcanic edifice exists in Shaerbuti Mountain. Based on geochemical features, the Shaerbuti volcanic rocks have been identified as being of two types. Type I volcanic rocks have light rare earth element (LREE)-enriched patterns, with La/Sm ratios of 2.27–4.03, Th/Yb ratios of 0.50–1.46, and Nb/Yb ratios of 1.11–2.28. Type II volcanic rocks display a flat rare earth element (REE) pattern, with La/Sm ratios ranging from 1.83 to 2.43, Th/Yb ratios ranging from 0.24 to 0.45, and Nb/Yb ratios ranging from 0.87 to 0.93. In the studied rocks, MgO-Cr, MgO-Ni and MgO-CaO present a positive relationship, which indicates clinopyroxenes crystallized. The Sr-Nd-Pb isotopic compositions of these basalts present values of 0.7045 to 0.7063 ((87Sr/86Sr)i), 6.4 to 6.6 (εNd(t)), and 17.1300 to 18.3477 ((206Pb/204Pb)i), respectively. According to Sr-Nd-Pb isotope features, we argue that melts of altered oceanic crust and sediments were incorporated into the source. We also evaluate the water content (0.55%–6.72%) of the studied volcanic rocks.

МЕДИСТЫЕ СЛАНЦЫ ПРИКОЛЫМСКОГО ТЕРРЕЙНА (СЕВЕРО-ВОСТОК РОССИИ): МИНЕРАЛОГО-ГЕОХИМИЧЕСКИЕ ОСОБЕННОСТИ И УСЛОВИЯ РУДООБРАЗОВАНИЯ

Copper mineralization in the Magadan region (North-East of Russia) has been established in quartz-chloritoid and chlorite shales of the middle and upper Riphean of the Prikolymsky terrane. Compared to the upper crust, copper shales of the Oroek deposit are noticeably enriched in a narrow range of trace elements: Cu, Ag, Au, Rh, and Se, with enrichment factors ranging from 10-fold (Se, Rh) to 100-fold (Ag, Au) and even 1000-fold (Cu) suggesting, apparently, their synchronous involvement in ore formation. In addition, the studied samples are slightly enriched in Cd, Li, Co, Zn, V, U, Sc, Y, and REE. Copper shales show relatively flat rare earth element (REE) patterns similar to the chondrite-normalized pattern having no distinct positive or negative Eu anomalies and dominated by light lanthanides. The Ce/Ce* and Eu/Eu* values indicate that ore formation proceeded under oxidizing conditions. The obtained geochemical data show that the Riphean host rocks could serve as a source of trace elements and REE ore-forming fluids. In the ores, covellin and chalcocite are the main copper minerals; less common are roxbyite, idaite, nukundamite, spioncopite, chalcopyrite, silver-bearing (Ag about 1 wt. %) bornite and yarrovite, as well as native gold. Fluid inclusions in quartz suggest that copper mineralization was formed at temperatures of 212–190 °C and a pressure of 1 kbar, from hydrothermal solutions of medium salinity (from 13.8 to 12.4 wt. % eq. NaCl) and high density (0.95–0.98 g/cm3) saturated with chlorides of Ca, Mg, and K. The copper shales of the Prikolymsky terrane differ from sedimentary copper and copper shales of the African Belt by low Co and Ni contents and from the Kupfershifer by low concentrations of Pb and Zn. The obtained results can be used for prognosticating new deposits.

Syn-orogenic tectonomagmatic evolution of the Qilian Orogen: Insights from the Lumanshan gabbro–granite association in the Qilian Block, Northwest China

Gabbro–granite associations provide critical geological clues for unraveling crust–mantle interactions, regional tectonics and geodynamic processes. Many Late Ordovician–Early Devonian granitoids occur in the Qilian Block, display high-K calc-alkaline affinities but have less well-constrained geodynamic mechanisms. Here, we report the newly discovered Late Ordovician-Early Devonian Lumanshan (LMS) gabbro–granite association in the Qilian Block that is composed mainly of syenogranites and alkali-feldspar granites, with minor gabbro. Zircon U Pb dating yields crystallization ages of ca. 440 Ma for the gabbros and ca. 450 Ma and 414 Ma for the syenogranite and alkali-feldspar granite, respectively. The gabbros are calc-alkaline series and display enriched mid-ocean ridge basalt ( E -MORB)-like rare earth element (REE) patterns; U, Cs, and Rb enrichments; Nb, Ta, Zr, and Hf depletions; and depleted Sr–Nd–Hf isotope compositions. The results indicate that the gabbros were possibly derived from partial melting of an asthenospheric mantle wedge metasomatized by aqueous fluids. Two granite types within the LMS pluton are peraluminous and have a transitional geochemical affinity between S- and I-type, low Mg# values, and similarly evolved Sr Nd isotope compositions, which overlap with those of Neoproterozoic basement rocks exposed in the study area. The syenogranites show adakitic geochemical characteristics with high La/Yb and Nb/Ta ratios, whereas the alkali-feldspar granites are non-adakitic granites with flat heavy REE patterns and significant Ba, Sr, and Eu depletions, suggesting that they formed at lower and middle crustal levels, respectively. The LMS ca. 450–440 Ma gabbro and syenogranite were emplaced during a back-arc extensional regime associated with roll-back of the northward-subducting South Qilian Ocean slab. Synthesized data from this and previous studies suggest that the final closure of the South Qilian Ocean and continental collision between the Qilian and Qaidam blocks likely occurred at ca. 435 Ma, and the ca. 414 Ma LMS alkali-feldspar granites generated in syn -collisional setting related with exhumation of the subducted continental crust. The LMS alkali-feldspar granites also show decoupled Nd Hf isotopic systems, which should result from significant disequilibrium melting of metasedimentary materials with the apparent abundance of inherited zircons in their source due to a less intense thermal regime. • A gabbro–granite association in the Qilian Block formed in early–middle Paleozoic. • The ca. 472–435 Ma magmatism formed in an extensional setting related to slab roll-back. • The ca. 435–400 Ma magmatism occurred in syn-collisional setting.

Shidian meteorite, a new fall analog of near‐Earth asteroid (101955) Bennu

AbstractShidian is a recent meteorite which fell in Yunnan province, China, on November 27, 2017, and has been classified as a CM2 chondrite. Petrography, mineralogy, oxygen and chromium isotopic composition, reflectance spectrum, and density studies of Shidian are reported in this study. Clasts with different aqueous alteration degree, two type 1 clasts with nontypical CM petrography, and one metamorphic clast are observed in Shidian. Mineralogically, Shidian main body consists of phyllosilicates (∼70 vol%), forsterite (∼13 vol%), fayalitic olivine, carbonates, sulfide, high‐Ca pyroxene, magnetite framboids, and Fe‐Ni metal. The average electron microprobe analysis (EMPA) analytical totals of phyllosilicates are 84.07 ± 1.75 wt%, with average FeO/SiO2 of tochilinite–cronstedtite intergrowths (TCIs) in different clasts ranging from 1.18 to 3.29. The bulk geochemical composition is characterized by flat rare earth element pattern, and by depletion of highly volatile elements. The whole rock oxygen isotopic composition is −0.51 ± 0.73‰, 5.44 ± 1.01‰, and −3.38 ± 0.20‰ for δ17O, δ18O, and Δ17O, respectively, with bulk chromium isotopic composition as ε54Cr = 1.00 ± 0.11. The grain density, bulk density, and porosity are 2.758 ± 0.008 g cm−3, 2.500 ± 0.004 g cm−3, and 9.37 ± 0.59%, respectively. The reflectance spectrum shows “blue” (negative) continuum slope across the visible and near‐infrared range, with characteristic absorption features (such as 0.765, 0.923, and 1.160 μm for phyllosilicates). These characteristics indicate that Shidian is an unheated, brecciated CM chondrite and may be an analog of asteroid Bennu.

Geochemistry of meta‐mafic and meta‐tonalite‐trondhjemite intrusives from Jaintia and Karbi Anglong hills of Shillong Plateau, North East India: Implications on the evolution of the Proterozoic Shillong Basin

We present the whole‐rock and mineral chemical data of the Khasi meta‐mafic/basic‐trondhjemite intrusives (KMI) and meta‐tonalite‐trondhjemite (MTT) that coevally emplaced the Proterozoic Shillong Group (SG) of Shillong Plateau, northeast (NE) India and discuss their petrogenetic‐tectonic origin. The calc‐alkaline to tholeiite KMI are compositionally transitional between hornblende‐gabbro; hornblende‐diorite and minor‐hornblendite. They show Ta–Nb troughs and strong decoupling large‐ion lithophile/high field strength elements (HFSE) signature consistent with subduction zone‐related basic magmas. The calcic to calc‐alkaline, low‐Al2O3, and I‐type metaluminous Fe‐hedenbergite‐trondhjemite (KMT) exhibits similar trace and rare earth elements (REE) distribution to the KMI. The MTT on the other hand are depleted in trace elements and REE, and correspond with the I‐type granitoids, and are comparable to Proterozoic to Phanerozoic tonalite‐trondhjemite‐granodiorites. Gentle negative sloping of REE in KMI ([La/Lu]CN = 4.04 to 6.35) with moderate LREE, suggests partial melting or, fractional crystallization from a transitional source between garnet and spinel lherzolite. Although almost a flat pattern ([La/Lu]CN = 3.70 to 4.05) for MTT entails a high degree of partial melting from sources similar to Archaean Mafic Composite or Archaean Tholeiite. Trace elemental modellings ([Sr/Y] vs. Y and [La/Yb]N vs. YbN) for MTT infer low pressure (<15 kbar) and high degree partial melting of >50% in equilibrium with 10% garnet +90% amphibole residue. A relatively flat REE pattern with some elevated HREE of MTT compared to KMI suggests for depleted source. Bimodal plutonism and the prevalence of meta‐dacite‐rhyolite in SG invokes for tonalite‐trondhjemite‐dacite setting of a continental arc or, active continental margin tectonic setting. Emplacement of KMI initiated in a temporary relax‐extensional phase and MTT in a compressional regime. This is possibly caused by an over‐thickened crust later subjected to orogenic collapse, exhumation‐metamorphism, and decompressional melting. This event might have taken place between 1.0 to 0.5 Ga during the Pan‐African Orogenic crustal growth, linked to the amalgamation of Gondwana.

Modern-style plate tectonics manifested by the late Neoarchean TTG-sanukitoid suite from the Datong-Huai'an Complex, Trans-North China Orogen

When modern-style plate tectonics started and operated on a specific old craton has been a key point involving the early Earth's evolution. In order to address this issue on the evolution of the Neoarchean North China Craton (NCC), we investigated a representative successive magmatic rock suite of tonalite-trondhjemite-granodiorite (TTG) and sanukitoid in the Datong-Huai'an Complex. Geochemically, TTG gneisses in the Datong-Huai'an Complex can be divided into high-pressure (HP) and low-pressure (LP) TTG rocks. The HP TTGs emplaced at ∼2538–2497 Ma and 2441 Ma, respectively. Geochemical data shows that they are characterized by steep rare earth element (REE) patterns, obvious negative Nb, Ta, Ti anomalies and positive δEu anomalies, high Sr/Y, Nb/Ta and (La/Yb) N ratios, and positive ɛ Hf (t) (+2.1 to +9.1) and δ 18 O values (avg. 5.5‰ to 6.0‰). Their protolith is interpreted as the consequence of partial melting of a subducted oceanic slab with garnet and minor rutile as residual phases. In contrast, the LP TTGs emplaced at ∼2518 Ma. They display flat REE patterns, slightly negative Nb, Ta, Ti anomalies and negative δEu anomalies, low Sr/Y, Nb/Ta and (La/Yb) N ratios, positive ɛ Hf (t) (+3.4 to +5.9) and high δ 18 O values (avg. 5.9‰ to 6.1‰). They were most likely generated by partial melting of the mafic lower crust with residual plagioclase and amphibolite in the source region. The sanukitoid rocks emplaced at 2517–2485 Ma and show high MgO, Cr and Ni concentrations but relatively low (La/Yb) N values, positive ɛ Hf ( t ) values (+1.5 to +5.4), and higher δ 18 O values (avg. 6.8‰ to 7.5‰), suggesting that they were originated from partial melting of the mantle peridotite that was previously modified by slab-derived or sediment-derived melts. Combined with previous petrological, geochronological and geochemical data, we propose that the Datong-Huai'an Complex recorded the prolonged magmatism through ca. 2.56 Ga to 2.44 Ga, which was characterized by the high-angle subduction of oceanic lithosphere, leading to the opening of a mantle wedge, slab rollback and back-arc extension. All these lines of evidence manifested that a modern-style plate tectonics regime started along the western margin of the NCC Eastern Block during the late Neoarchean, though the interior Eastern Block was still dominated by the mantle plume-induced crustal growth and vertical tectonism. • Coeval TTGs and sanukitoids were recognized in the Datong-Huai’an Complex. • They recorded the prolonged high-angle subduction with rollback and back-arc extension. • Modern-style plate tectonics started along the margin of NCC Eastern Block in late Neoarchean.

Petrogenesis of low-pressure intra-oceanic arc granitoids: Insights from the late Neoproterozoic Avalonian–Cadomian orogen, Bohemian Massif

The processes leading to the formation of siliceous (intermediate to felsic) magmatic rocks from juvenile sources within intra-oceanic island arcs govern the formation of continental crust and tempos of crustal growth. To unravel the predominant process responsible for the formation of the intermediate to felsic intra-oceanic arc crust, we performed inverse geochemical modelling using major elements and fluid-immobile trace elements. Subvolcanic trondhjemite from a volcanic arc – Davle volcanic complex (DVC) situated in the Teplá–Barrandian unit, Bohemian Massif – that formed during the Neoproterozoic Avalonian–Cadomian orogeny was used as a proxy for the most felsic endmember of the tonalite–trondhjemite suite. The DVC trondhjemite that follows the calc-alkaline trend is enriched in several fluid-mobile elements such as Cs, Ba and U, but depleted in high field strength elements (Nb, Ti) and lithophile elements (e.g., K, Rb, Sr and Th), and exhibits flat rare earth element (REE) primitive mantle-normalized distributions with slightly negative Eu anomalies. Together with the largely radiogenic Hf-Nd isotopic signatures (ε Nd +6.0 to +8.7 and ε Hf +10.2 to +11.7), these data indicate formation in an intra-oceanic arc setting with no significant assimilation of older crustal material. In general, the composition of the studied trondhjemite markedly resembles that of other intra-oceanic arc-derived tonalites and trondhjemites worldwide, formed at low pressures below the garnet stability field. These are herein referred to as “low-pressure intra-oceanic arc granitoids” or “LP IOAG”. The performed inverse geochemical modelling revealed that dehydration partial melting or fractional crystallization of a mafic source can produce a primitive tonalitic melt. Consequently, fractional crystallization of that melt accounts for the compositional heterogeneity observed within the tonalite–trondhjemite suite. We conclude that LP IOAG, commonly forming large portions of intra-oceanic arc middle crust, can form in a nearly closed system with a negligible contribution of subduction-related melts or assimilation of older siliceous crust. Therefore, our findings suggest that the formation of LP IOAG within oceanic crust may represent the predominant process of post-Archean crustal growth. • The DVC trondhjemite has flat REE patterns resembling typical LP IOAG. • The LP IOAG play a key role in the post-Archean crustal growth. • The source composition is established by an inverse geochemical modelling. • The trondhjemite formed by fractional crystallization of a tonalitic source.

Development of Open Transport of Aqueous Fluid from Pegmatite Revealed by Trace Elements in Garnet

We investigated the fluid flow and elemental transport from a granitic body to the middle crust by determining the trace element compositions of garnet in pegmatites related to a quartz diorite intrusion and metamorphic rocks on Kinkasan Island, northeast Japan. Garnet in the pegmatites and biotite schists is characterized by spessartine– (Sps–) almandine- (Alm-) rich compositions of Sps14–69Alm22–70Prp2–14Grs1–13 and Sps16–30Alm54–66Prp9–16Grs3–6, respectively. A garnetite pod in the metamorphic unit has grossular- (Grs-) rich compositions (Sps1–4Alm8–11Prp0.1–0.4Grs80–87Adr3–4). The peak temperature ( T ) and pressure ( P ) conditions of the biotite schist during contact metamorphism were 600–650°C and 0.27–0.41 GPa, respectively. The primary fluid inclusions in quartz crystals within the pegmatites hosted by the quartz diorite and hosted by the metamorphic rocks have a wide range of homogenization temperatures (200–380°C). These correspond to the trapping temperature of 500–700°C, assuming a salinity of 4 wt.% NaClequivalent at pressure of the crystallization of the quartz diorite. Chondrite-normalized rare earth element (REE) patterns of garnets in the pegmatites in the quartz diorite and metamorphic unit are generally characterized by enrichment of heavy REEs and negative Eu anomalies with the REE contents in the schists which are systematically lower than in the pegmatites. However, garnet in the biotite schists close to the pegmatites has similar REE contents to garnet in the adjacent pegmatites. These geochemical features suggest that garnet in the biotite schists grew in response to fluid infiltration from the pegmatites. Besides, the Grs-rich garnet in the garnetite pod and its host quartz schist have flat heavy REE patterns and no Eu anomalies, which probably reflect a metasomatic process related to plagioclase replacement that produced Ca-Al-rich fluids. Our results suggest that the infiltration of pegmatitic fluids enhances elemental transport and metamorphic reactions in the middle crust.

Origin and re-Os geochronology of vein bitumen in the Nanpanjiang basin, SW China: Implication for the ore-forming age of Carlin-type gold deposits

The Nanpanjiang basin has the second-largest concentration of Carlin-type gold deposits in the world. Although significant progress has been made during the past two decades, the age of gold mineralization has not been well constrained. Field observation shows that these gold deposits are spatially associated with hydrocarbon reservoirs. At the Lannigou gold deposit, solid bitumens exist as films within structural fractures and cut through the orebodies, indicating that these bitumens formed after gold mineralization. In this work, we systematically studied bitumen reflectance (Rb), trace element, carbon isotope, and Re-Os isotopic compositions. These results show that these bitumens have high Rb values ranging from 2.40 to 2.71, indicating that they are high-maturity pyrobitumen. Trace element analysis reveals that bitumens in the deposit have high V/Ni, V/(V + Ni), and Zr/Sc ratios, but low Ni/Co, La/Sc ratios, and exhibit relatively flat rare-earth element (REE) patterns with no obvious Ce or Eu anomalies, comparable to the corresponding elemental ratios and REE patterns of Permian source rocks in the region. These bitumens also have similar δ13C values (-24.4 ‰ to –23.8 ‰, mean = -24.1 ‰) to the Permian source rocks (–22.4 ‰ to 24.7 ‰, mean = –23.6 ‰), indicating that they originate from the Permian source rocks. Five bitumen samples cut through the orebody yield a well-defined isochron age of 173 ± 6 Ma, indicating that the Lannigou gold deposit formed before this time. Our new data, combined with previously published geochronological data, suggest that the majority of Carlin-type gold deposits in the Nanpanjiang basin were mineralized at late Triassic to early Jurassic. The Re-Os data of this study also imply that the bitumen Re-Os chronometer has a large potential to constrain the timing of metal mineralization in low-temperature hydrothermal deposits.

Structure, geochronology, and petrogenesis of Permian peraluminous granite dykes in the southern Chinese Altai as indicators of Altai−East Junggar convergence

How and at which thermal conditions the convergence between the Chinese Altai and East Junggar operated remain poorly understood. This issue is addressed in the current study by focusing on the timing and petrogenesis of syntectonic granite dykes from the representative areas of Fuyun (convergent front) and Kalasu-Aletai (Chinese Altai interior). It is shown that Fuyun and Kalasu-Aletai dykes are fractionated I- and S-type granites, with zircon and monazite U-Pb ages of 300−291 Ma and 281−265 Ma, respectively. Geochemically, the Fuyun dykes have lower contents of aluminous (ASI: 0.97−1.13) and light rare earth element-enriched features, while the Kalasu-Aletai dykes have ASI = 1.01−2.17 and show overall flat rare earth element patterns with tetrad effects. The Fuyun dykes exhibit less evolved Sr-Nd isotopic characteristics (87Sr/86Srinitial: 0.7039−0.7048, εNd(t): + 5.7 to + 6.1) with respect to those of the Kalasu-Aletai dykes (87Sr/86Srinitial: 0.6978−0.7183, εNd(t): −7.6 to +3.0). The Fuyun and Kalasu-Aletai dykes are geochemically compatible with isotopically less evolved East Junggar arc components and heterogeneous Ordovician wedge sediment of the Chinese Altai, respectively, implying genetic links. We propose that the late Paleozoic Chinese Altai−Junggar convergence created a local perturbation of weak mantle beneath the southern Chinese Altai, causing partial melting of the underthrusting East Junggar and the overriding Altai components successively. The resulting magmas were emplaced along northward propagating syn-tectonic tensional fractures perpendicular to the Chinese Altai−East Junggar deformation front that serves as an excellent indicator of the convergent-shortening process.